Direct Glycosylations with 1-Hydroxy Glycosyl Donors Using Trifluoromethanesulfonic Anhydride and Diphenyl Sulfoxide. -A new method for glycosidic bond construction is described involving in situ activation of the anomeric hydroxyl. This one-step procedure is applicable directly to the glycosylatio
Direct Glycosylations with 1-Hydroxy Glycosyl Donors using Trifluoromethanesulfonic Anhydride and Diphenyl Sulfoxide
β Scribed by Garcia, Brian A.; Poole, Jennifer L.; Gin, David Y.
- Book ID
- 120896531
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 104 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
An efficient and direct one-pot glycosylation method using anomeric hydroxy sugars as glycosyl donors, employing 3-fluorophthalic anhydride and triflic anhydride as activating agents, has been developed. The present glycosylation utilizing 3-fluorophthalic anhydride resulted in few to no undesired s
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