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Direct formation of a state-selected excited state of Fe atoms by multiphoton dissociation of Fe(CO)5 at atomic transition frequencies

✍ Scribed by K. Lee; J.S. Goo; J.K. Ku


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
378 KB
Volume
244
Category
Article
ISSN
0009-2614

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✦ Synopsis


When an unfocused laser beam with narrow linewidth whose frequency matches exactly an atomic transition line of the Fe atom was passed through a gas mixture containing Fe(CO)5, atomic emissions from the state-selected excited state of Fe atoms were observed. The power dependence of the emission intensities as well as excitation and fluorescence spectra suggested that the state-selected excited state Fe atoms are generated by one-photon absorption of the ground state Fe atoms formed by two-photon dissociation of Fe(CO) 5 within a single laser pulse.