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Direct Evidence for Oxygen-Atom Exchange between Nonheme Oxoiron(IV) Complexes and Isotopically Labeled Water

โœ Scribed by Mi Sook Seo; Jun-Hee In; Sun Ok Kim; Na Young Oh; Jongki Hong; Jinheung Kim; Lawrence Que Jr.; Wonwoo Nam


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
138 KB
Volume
116
Category
Article
ISSN
0044-8249

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Direct Evidence for Oxygen-Atom Exchange
โœ Mi Sook Seo; Jun-Hee In; Sun Ok Kim; Na Young Oh; Jongki Hong; Jinheung Kim; Law ๐Ÿ“‚ Article ๐Ÿ“… 2004 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 139 KB

Complexes 1 and 2 were prepared by treating [Fe(TMC)(OTf) 2 ] (2 mm) and [Fe(N4Py)(ClO 4 ) 2 ] (2 mm), respectively, with 1 equivalent of peracid (peracetic acid for 1 and m-chloroperbenzoic acid for 2) in CH 3 CN (3 mL) at 10 8C. [7] After appropriate amounts of H 2 18 O were added to the reaction