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Direct electrochemical synthesis and crystal structure of tris(pyridine-2-selenolato)indium(III)

✍ Scribed by Jaime Romero; Maria L. Durán; Jose A. García-Vázquez; Alfonso Castiñeiras; Antonio Sousa; Léon Christiaens; Jon Zubieta

Book ID
108328448
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
522 KB
Volume
255
Category
Article
ISSN
0020-1693

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A series of mixed cobalt(III) complexes [Co(pySe) 3 -n (N N) n ] n + [pySe= pyridine-2-selenolato (1 -); N N= 1,2-ethanediamine (en) and 2,2%-bipyridine (bpy); n= 0, 1 and 2] was prepared. The geometrical preference and trans influence of pySe are fairly different from those of pyridine-2-thiolate.