## Abstract The relativeβrate method has been used to determine the rate coefficients for the reactions of OH radicals with three C~5~ biogenic alcohols, 2βmethylβ3βbutenβ2βol (__k__~1~), 3βmethylβ3βbutenβ1βol (__k__~2~), and 3βmethylβ2βbutenβ1βol (__k__~3~), in the gas phase. OH radicals were prod
Direct Determination of the Rate Coefficient for the Reaction of OH Radicals with Monoethanol Amine (MEA) from 296 to 510 K
β Scribed by Onel, L.; Blitz, M. A.; Seakins, P. W.
- Book ID
- 126236877
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 478 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1948-7185
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π SIMILAR VOLUMES
Absolute rate constants have been measured for the reaction of the OH radical with diacetylene over the temperature range of 296-688K using a flash photolysis-resonance fluorescence technique. The best fit to the data is given by the following Arrhenius expression: k= 1.11 x 10 -II exp{410+3OO(cal/m
Using a relative rate technique, rate constants for the gas-phase reactions of the OH radical with the three cresols and the six dimethylphenols have been determined a t 296 t 2 K and atmospheric pressure. The rate constants for the cresols, which range from 4.3 x lo-" cm3 molecule-' s-' to 6.8 x lo
Using a relative rate method, rate constants have been determined at 296 5 2 K for the gas-phase reactions of the OH radical with toluene, the xylenes, and the trimethylbenzenes. Using the recommended literature rate constant for the reaction of OH radicals with propene of (2.66 2 0.40) x lo-" cm3 m
Rate constants for the gas-phase reactions of 0 3 with the sesquiterpenes a-cedrene, a-copaene, P-caryophyllene, a-humulene, and longifolene, and with the monoterpenes limonene, terpinolene, a-phellandrene, and a-terpinene, have been measured using a relative rate technique at 296 5 2 K and atmosphe
Rate coefficients for the reaction of OH with Cl 2 , (k 1 ), Br 2 , (k 2 ) and I 2 , (k 3 ), were measured under pseudo-first-order conditions in OH. OH was produced by pulsed laser photolysis of H 2 O 2 (or HNO 3 ) and its temporal profile was monitored by laser-induced fluorescence. The measured r