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Direct Cross-Coupling of CH Bonds with Grignard Reagents through Cobalt Catalysis

✍ Scribed by Prof. Dr. Bin Li; Zhen-Hua Wu; Yi-Fan Gu; Chang-Liang Sun; Prof. Dr. Bai-Quan Wang; Prof. Dr. Zhang-Jie Shi

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
370 KB
Volume
123
Category
Article
ISSN
0044-8249

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Cobalt-Catalyzed Cross-Coupling Reaction
Cobalt-Catalyzed Cross-Coupling Reactions of Alkyl Halides with Allylic and Benzylic Grignard Reagents and Their Application to Tandem Radical Cyclization/Cross-Coupling Reactions
✍ Hirohisa Ohmiya; Takashi Tsuji; Hideki Yorimitsu; Koichiro Oshima 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 317 KB 👁 1 views

## Abstract Details of cobalt‐catalyzed cross‐coupling reactions of alkyl halides with allylic Grignard reagents are disclosed. A combination of cobalt(II) chloride and 1,2‐bis(diphenylphosphino)ethane (DPPE) or 1,3‐bis(diphenylphosphino)propane (DPPP) is suitable as a precatalyst and allows second