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Direct Conversion of sec-Phosphine Oxides into Phosphinous Acid-Boranes.

โœ Scribed by Marek Stankevic; Grzegorz Andrijewski; K. Michal Pietrusiewicz


Publisher
John Wiley and Sons
Year
2004
Weight
94 KB
Volume
35
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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Direct conversion of secondary phosphine
โœ Anna Hubacz; Slawomir Makowiec ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 142 KB

The reaction of [di(acyloxy)iodo]benzene with secondary phosphine oxides or H-phosphinates in the presence of primary or secondary amines allows one to obtain phosphinic or phosphonic acids amides in the one-pot process. We take advantage of the strong acylating system DAIB/R 2 P(O)H to phosphinylat