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Direct conversion of aliphatic carboxamides to alkylammonium tosylates with [hydroxy(tosyloxy)iodo]benzene

โœ Scribed by Lazbin, I. Mark; Koser, Gerald F.


Book ID
120406986
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
432 KB
Volume
51
Category
Article
ISSN
0022-3263

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โœ Anna Hubacz; Slawomir Makowiec ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 142 KB

The reaction of [di(acyloxy)iodo]benzene with secondary phosphine oxides or H-phosphinates in the presence of primary or secondary amines allows one to obtain phosphinic or phosphonic acids amides in the one-pot process. We take advantage of the strong acylating system DAIB/R 2 P(O)H to phosphinylat