Poly(triacetylene) Oligomers: Conformati
✍
Michael J. Edelmann; Michael A. Estermann; Volker Gramlich; François Diederich
📂
Article
📅
2001
🏛
John Wiley and Sons
🌐
German
⚖ 132 KB
Starting from the octameric poly(triacetylene) (PTA) oligomer 1e as a large macromonomer, the monodisperse tetracosamer (24-mer) 1h was prepared by a previously introduced statistical deprotectionoligomerization sequence (Scheme). It is the longest known molecular rod featuring a fully conjugated, n