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Direct Chromatographic Separation of Racemates on the Basis of Isotopic Chirality

โœ Scribed by Kimata, Kazuhiro; Hosoya, Ken; Araki, Takeo; Tanaka, Nobuo

Book ID
126126289
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
103 KB
Volume
69
Category
Article
ISSN
0003-2700

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An unprecedented isotope effect on rr-rr face to edge interaction was observed in the separations of the enantiomers of the pivalamide of e(,od-phenyl-(phenyl-d5)methylamine 3a, and the p,p' disubstituted analogs on CSP 2. The configuration of the more retained enantiomer of its p,p'-dibromo derivat