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Direct C -Glycosylation of Organotrifluoroborates with Glycosyl Fluorides and Its Application to the Total Synthesis of (+)-Varitriol

✍ Scribed by Zeng, Jing; Vedachalam, Seenuvasan; Xiang, Shaohua; Liu, Xue-Wei


Book ID
120014785
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
430 KB
Volume
13
Category
Article
ISSN
1523-7060

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Samarium Diiodide Promoted C-Glycosylati
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The synthesis of the C-glycoside analogue of the disaccharide Man-(a1 32)Man has been achieved in a highly stereoselective and efficient manner employing an approach which closely parallels O-glycoside synthesis. The key step included the samarium diiodide reduction of mannosyl pyridylsulfone 18 in