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Direct Assignment of the Relative Configuration in 1,3, n -Methyl-Branched Carbon Chains by 1 H NMR Spectroscopy

โœ Scribed by Schmidt, Yvonne; Breit, Bernhard


Book ID
126986039
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
590 KB
Volume
12
Category
Article
ISSN
1523-7060

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Assignment of relative configurations to
โœ C. Alvarez Ibarra; M. L. Quiroga Feijoo; M. S. Arias Perez; J. de la Orden Parra ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 423 KB

An assignment of relative configurations has been achieved for the diastereomeric racernates(lR2R,lS2S) and (1R2S, 1S2R) of 3,3-dimethyl-l,2-diphenylbuta~-l-ol through the comparative analysis of the respective chemical shifts induced by Eu(fod), in the 'H and '"C NMR spectra, and the corresponding