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Direct arylation of phenanthroline derivatives via oxidative C–H/C–H cross-coupling: synthesis and discovery of excellent ligands

✍ Scribed by Li, Bijin; Qin, Xurong; You, Jingsong; Cong, Xuefeng; Lan, Jingbo

Book ID
118246246
Publisher
Royal Society of Chemistry
Year
2013
Tongue
English
Weight
418 KB
Volume
11
Category
Article
ISSN
1477-0520

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In 1972, a very powerful catalytic cycle for carbon-carbon bond formation was 2 first discovered by the coupling reaction of Grignard reagents at the sp -carbon. Over the past 30 years, the protocol has been substantially improved and expanded to other coupling reactions of Li,B,N,O,Al,Si,P,S,Cu,Mn,