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Direct and sensitized photoproduction of free radicals in ethanol glasses: A comparative ESR study

✍ Scribed by F. Lenci; H. Neubacher


Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
317 KB
Volume
16
Category
Article
ISSN
0009-2614

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✦ Synopsis


Light-induced radical production and transformations were investigated by ESR at 77Β°K in pure ethanol and in ethanol solutions of 2-amkopyrimidine, proflavine and diphenylarnine. Differences in the ESR spectra are explained by different yields of light-induced radica! transformations

The primary radical species formed by photosensitization and by direct UV bond splitting are su_egested to be the same.


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## Abstract Iminoxy radicals of a new type, having the general formula RC(ο£ΎNO^Λ™^)P(O)(OEt)~2~, were synthesized and characterized by means of ESR spectroscopy. The presence of two isomers due to the different position of the Cο£ΎNOΛ™ fragment with respect to the R substituent and the P atom, and the r