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Direct and Inverse Reactivity-Selectivity Relationship in the [1.2]-Addition of Singlet Carbenes to Olefins

โœ Scribed by Priv.-Doz. Dr. Wolfgang W. Schoeller

Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
208 KB
Volume
20
Category
Article
ISSN
0044-8249

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The Addition of 2-Oxido-2-cyclopenten-1-
The Addition of 2-Oxido-2-cyclopenten-1-ylium to Some Olefins and Dienes in 2,2,2-Trifluoroethanol
โœ Johannes Leitich; Ingeborg Heise ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 448 KB

The title reaction has been studied with 2-methoxypropene, (E)-cyclooctene, ethoxyethene, 1,3-cyclopentadiene, 3methylenecyclohexene, styrene and isoprene as the olefinic substrates. This sequence is one of decreasing reactivity of the substrates towards 2-oxido-2-cyclopenten-1-ylium (1) if [4 + 3]