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Dipole moments, structure, and transannular interactions in silatranes containing planar fragments

โœ Scribed by E. A. Ishmaeva; A. P. Timosheva; A. A. Gazizova; D. V. Chachkov; Ya. A. Vereshchagina; V. E. Kataev; N. V. Timosheva


Book ID
111459728
Publisher
Springer
Year
2008
Tongue
English
Weight
179 KB
Volume
78
Category
Article
ISSN
1070-3632

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Structural aspects of a possible transan
โœ Tor Dahl; Per N. Skancke ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 769 KB

Complete geometry optimizations using ab initio SCF/3-21G\* calculations were performed on silatrane and azasilatrane, on their fluoro derivatives, and on methylsilatrane. By comparison with optimized geometries obtained for a series of model systems, the predicted transannular internuclear distance