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Dipole moments and conformational equilibrium in some substituted 1-phenyl-1-fluoro-2-halogenoethanes

✍ Scribed by C. Charlon; A.-M. Galy; C. Luuduc; J. Barbe

Publisher: John Wiley and Sons
Year: 1984
Tongue: English
Weight: 263 KB
Volume: 73
Category: Article
ISSN: 0022-3549
DOI: 10.1002/jps.2600730836

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✦ Synopsis

Experimental dipole moments of substituted I-phenyl-I-fluoro-2-halogenoethanes are compared with the vectorially and the theoretically calculated values using the C N D 0 / 2 method. Results support the existence of a conformational mixture of these compounds as solutes; gauche structures are the prevailing conformations as in the related catecholamines.

Keyphrases Phenylfluorohalogenoethanes-substituted, dipole moments, conformations as solutes 0 Dipole moments-substituted phenylfluorohalogenoethanes as solutes 0 Conformations-phenylfluorohalogenoethanes as solutes

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