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Dipole-Moment Derivatives of Nitrous Oxide

✍ Scribed by E.I. Lobodenko; V.I. Perevalov; O.M. Lyulin; J.-L. Teffo

Publisher: Elsevier Science
Year: 2001
Tongue: English
Weight: 247 KB
Volume: 205
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.2000.8269

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✦ Synopsis

The equations relating the q(2)J-type parameters of the matrix elements of the effective dipole-moment operator with the force field constants and the dipole-moment derivatives have been established by means of contact transformations in the case of nitrous oxide molecule. The effective dipole-moment operator corresponds to the reduced effective Hamiltonian derived by J.-L. Teffo, V. I. Perevalov, and O. M. Lyulin (J. Mol. Spectrosc. 168, 390-403 (1994)) for the global treatment of the vibrational-rotational energy levels of this molecule. Using these equations, the first and second derivatives of the dipole-moment function of the nitrous oxide molecule have been determined from the published values (O. M. Lyulin, V. I. Perevalov, and J.-L. Teffo, J. Mol. Spectrosc. 174, 566-580 (1995)) of the matrix element parameters of the effective dipole-moment operator. Copyright 2001 Academic Press.

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