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Dipolar recoupling of I = 1/2, S = 3/2 spin pairs with SEDOR for static and spinning samples

✍ Scribed by Terry Gullion


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
106 KB
Volume
45
Category
Article
ISSN
0749-1581

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✦ Synopsis


Spin-echo, double-resonance (SEDOR) dipolar recoupling experiments are illustrated on an I = 1/2, S = 3/2 spin system for static and spinning samples. An 15 N-23 Na spin system is used to show that the simple pulse sequence is very effective in causing 15 N dipolar dephasing using either a 23 Na p/2 recoupling pulse or a long radio-frequency (r.f.) recoupling pulse.


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