Dipolar magnetic field effects in NMR spectra of liquids
โ Scribed by C. Gayathri; A.A. Bothner-By; P.C.M. Van Zijl; C. Maclean
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 334 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Drpolrrr magnetic iicld cffccts ha\c been dcteckd m rhe NMR spectn oieoroncnc end mcrhylpyropheophorbtde UI hquld solu11on. Thcsc cficcls arose from rhc par1131 molecular abgnment mduccd by the magnelic field. Both 'H-*H uud *JC_ 'H couplinp 113~ been dclcctcd Tar both compounds the anisotropy III the dlamdgnctlc susceptlbihty 1s calculated 0.
๐ SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
We propose high-resolution magic angle spinning as a radical method for the suppression of dipolar field effects in liquid NMR. This technique works for any sample shape and any spatial distribution of nuclear magnetization. Furthermore, it removes any possibility of spectral clustering or instabili
An expression for the chemically induced dynamic electron polarization (CIDEP) in geminate radical pair recombinations is obtained within the recently proposed correct sudden approximation. This expression is valid for both low and high viscosities and reduces the problem to simple matrix operations