Dipolar cycloaddition of nitrones with (phenylsulfon,yl)propadiene give 4-sulfonyl substituted isoxazolidines whose reactions with base and several electrophiles have been studied.
Dipolar cycloaddition reactions of diazoindene and the thermal behavior of the cycloadducts
β Scribed by Padwa, Albert; Goldstein, Steven I.
- Book ID
- 119994121
- Publisher
- NRC Research Press
- Year
- 1984
- Tongue
- French
- Weight
- 622 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0008-4042
- DOI
- 10.1139/v84-429
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## Abstract The dipolar cycloaddition reaction of allenyl perfluoroalkyl sulfones (**1**) to nitrones (**2**) was described. Unlike nonfluorineβcontaining allenyl sulfones, **1** reacted readily with **2** in ether at room temperature and unusual zwitterionic cycloadducts (**3**) were obtained in g
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