Dipeptide Analogues Containing 4-Ethoxy-3-pyrrolin-2-ones
✍ Scribed by Hosseini, Masood; Kringelum, Henriette; Murray, Anthony; Tønder, Janne E.
- Book ID
- 118137262
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 78 KB
- Volume
- 8
- Category
- Article
- ISSN
- 1523-7060
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📜 SIMILAR VOLUMES
## Abstract Irradiation (λ =313 nm) of the 4‐pyrrolin‐3‐ones **1a–1c** in acetone‐, 3‐pentanone‐and cyclopentanone solution affords the title compounds **2**, formally __via__ H‐abstrac‐tion by the excited ketone and recombination of the radical pair formed.
Compounds previously reported to be 2,3,5\_trisubstituted 2pyrrolin-l-ones are shown to have 5,5'-dimeric structures. Recently, the reduction of 2,4,5-triphenyl-3H-pyrrol-3-one l-oxide (1) with Zn-HOAc was reported' to give 3-hydroxy-2,4,5\_triphenylpyrrole "2", (73%), where.