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Dioxygen Reduction at Dicobalt Complexes of a Schiff Base Calixpyrrole Ligand

✍ Scribed by Gonzalo Givaja; Manuel Volpe; Michael A. Edwards; Alexander J. Blake; Claire Wilson; Martin Schröder; Jason B. Love

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
165 KB
Volume
119
Category
Article
ISSN
0044-8249

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✦ Synopsis

We thank the EPSRC(UK) and the University of Nottingham for their support. M.S. gratefully acknowledges receipt of a Royal Society Wolfson Merit Award and of a Royal Society Leverhulme Trust Senior Research Fellowship.

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✍ Federico Franceschi; Geoffroy Guillemot; Euro Solari; Carlo Floriani; Nazzareno 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 241 KB 👁 1 views

A novel class of dinucleating ligands has been introduced into manganese chemistry to study the reactivity of this metal towards dioxygen under strictly controlled conditions. Such N 4 ligands combine some of the major peculiarities of tetradentate Schiff bases and the porphyrin skeleton. They are d