✦ LIBER ✦

Dioxomolybdenum(VI) complexes: relations between oxygen transfer and 95Mo NMR chemical shift

✍ Scribed by Helena Teruel; Anibal Sierralta

Book ID: 103997589
Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 365 KB
Volume: 107
Category: Article
ISSN: 1381-1169
DOI: 10.1016/1381-1169(95)00236-7

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✦ Synopsis

A relation between 95M0 NMR chemical shifts, semi-empirical CNDO estimated p and d orbital electron population and oxygen transfer capacity for a number of dioxomolybdenum(VI) complexes containing the unit [MoWOz ] is discussed. The way in which the oxo ligand electronic structure could influence on its oxygen transfer capacity, i.e. intermolecular or intramoleculafly is analyzed. Compounds exhibiting negative chemical shift are associated with nucleophilic attack to the oxo ligand and intermolecular oxygen transfer, while those showing a positive chemical shift are associated with intramolecular oxygen transfer.

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