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Diode laser detection of transient CF3 radicals formed by CO2 laser multiphoton induced dissociation of halocarbons

โœ Scribed by C.E. Brown; J.J. Orlando; J. Reid; D.R. Smith


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
339 KB
Volume
142
Category
Article
ISSN
0009-2614

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Infrared diode laser spectroscopic detec
โœ Ko-ichi Sugawara; Taisuke Nakanaga; Harutoshi Takeo; Chi Matsumura ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 382 KB

Infrared diode laser spectroscopy was applied to the detection of CF2 carbene produced by C02-laser-induced dissociation of CHCIF2. Time-resolved spectra of CF2 in several rotation-vibration states were observed. The initial concentration of CF2 was estimated to be 5x IO" molecules cm-' from an anal