Dinuclear Palladium, Nickel, and Rhodium Complexes Based on 1,3-Bis[(2-(diphenylphosphino)benzylidene)amino]propan-2-ol
β Scribed by van den Beuken, Esther K.; Veldman, Nora; Smeets, Wilberth J. J.; Spek, Anton L.; Feringa, Ben L.
- Book ID
- 120427434
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 349 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0276-7333
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## Abstract The solvolysis of __cis__(chloro)(1βaminoβpropanβ2βol)bis(ethylenediamine)cobalt(III) in aqueous alcoholic media using methanol, propanβ2βol, __t__βbutanol as cosolvents, resulted in the formation of the (N,O) chelated product__cis__[Co(en)~2~(NH~2~CH~2~CHOHCH~3~)]^3+^. The pseudo first
i'hirtyfour complexes of 1,2-bis(methylphenylarsino)ethane (dase) and I ,3-bis(methylphenybsrsino)propane (dasp) have been characterised. Interesting differences are observed in the complexing properties of these chelates. Thus, with cobalt(II) halides [Co-(dase)z] [CoX4], which contain planar catio