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Dinuclear Molybdenum and Tungsten Complexes with Metal−Metal Triple Bonds Supported by p - tert -Butylcalix[4]arene Ligands

✍ Scribed by Chisholm, Malcolm H.; Folting, Kirsten; Streib, William E.; Wu, De-Dong

Book ID
127276219
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
289 KB
Volume
38
Category
Article
ISSN
0020-1669

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Dinuclear Molybdenum(III) and Tungsten(I
Dinuclear Molybdenum(III) and Tungsten(III) Calix[4]arene Complexes − Metal-Metal Triple Bonds Supported by Bridging Calix[4]arene Ligands
✍ Udo Radius; Juri Attner 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 511 KB

Addition of p-tert-butylcalix[4]arene LH 4 to the dinuclear ported by two bridging µ 2 -κ 2 O,κ 2 O-calix[4]arene ligands in compounds M 2 (NMe 2 ) 6 (M = Mo, W) results in the formation the solid state. These compounds are the first examples of a of [NH 2 Me 2 ] 2 [L 2 M 2 ] 1 (M = Mo) and 2 (M = W