Dinuclear MnIII Compounds [{Mn(bpy)(H2O)}2(μ-4-RC6H4COO)2(μ-O)](NO3)2 (R = Me, F, CF3, MeO, tBu): Effect of the R Group on the Magnetic Properties and the Catalase Activity

New Dinuclear MnIII Compounds with 2-MeC

New Dinuclear MnIII Compounds with 2-MeC6H4COO and 2-FC6H4COO Bridges – Effect of Terminal Monodentate Ligands (H2O, ClO4– and NO3–) on the Magnetic Properties

✍ Gema Fernández; Montserrat Corbella; Gabriel Aullón; Miguel A. Maestro; José Mah 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 348 KB

## Abstract Four new dinuclear Mn^III^ complexes with the general formula [{Mn(bpy)L}(μ‐RCOO)~2~(μ‐O){Mn(bpy)L′}]^__n+__^ (bpy =2,2′‐bipyridine) have been synthesized with RCOO = 2‐MeC~6~H~4~COO (1, 2) and 2‐FC~6~H~4~COO (3, 4); the counteranion could be NO~3~^–^ (1, 3) or ClO~4~^–^ (2, 4), and a m