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Dinuclear macrocyclic palladium complexes having pincer coordinating groups and their catalytic properties in Mizoroki–Heck reactions

✍ Scribed by Taro Tsubomura; Mutsumi Chiba; Shogo Nagai; Mariko Ishihira; Kenji Matsumoto; Toshiaki Tsukuda


Book ID
116680180
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
293 KB
Volume
696
Category
Article
ISSN
0022-328X

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## Abstract Symmetrically and unsymmetrically substituted benzimidazolium bromides (1a–d = NHC·HBr) were synthesized, incorporating bulky benzyl and/or methoxyethyl substituents (a: R = pentamethylbenzyl, R′ = 2‐methoxyethyl; b: R = 2,3,5,6‐tetramethylbenzyl, R′ = methoxyethyl; c: R, R′ = pentameth