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Dinuclear (Fe II , Gd III ) Complexes Deriving from Hexadentate Schiff Bases: Synthesis, Structure, and Mössbauer and Magnetic Properties

✍ Scribed by Costes, Jean-Pierre; Clemente-Juan, Juan Modesto; Dahan, Françoise; Dumestre, Frédéric; Tuchagues, Jean-Pierre

Book ID: 124159240
Publisher: American Chemical Society
Year: 2002
Tongue: English
Weight: 100 KB
Volume: 41
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic0112793

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## Abstract Four cyanido‐bridged Mn^III^–Cr^I^ heterodimetallic complexes have been synthesized by the reactions of Mn^III^ Schiff‐base complexes with the [Cr(CN)~5~(NO)]^3–^ building block. X‐ray diffraction analysis reveals that [Mn(5‐Cl‐salen)(H~2~O)~2~][Mn~2~(5‐Cl‐salen)~2~(H~2~O)~1.5~Cr(CN)~5~