Dinuclear Copper(I) Thiolate Complexes with a Bridging Noninnocent PNP Ligand
✍ Scribed by Dr. Jarl Ivar van der Vlugt; Dr. Evgeny A. Pidko; Dr. Richard C. Bauer; Dr. Yann Gloaguen; Mark K. Rong; Dr. Martin Lutz
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 527 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0947-6539
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## Abstract Reactions of the thiolate‐bridged diruthenium complex [Ru(py^bu^S~4~)]~2~ (1) {py^bu^S~4~^2−^ = 2,6‐bis[(3,5‐di‐__tert__‐butyl‐2‐sulfanylphenyl)thiomethyl]pyridine(2−)} with small‐molecule ligands L afforded the corresponding mononuclear complexes [Ru(L)(py^bu^S~4~)] [L = H^−^ (2); CH~3