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Dinuclear complexes of tetravalent cerium in an aqueous perchloric acid solution

โœ Scribed by Ikeda-Ohno, Atsushi; Tsushima, Satoru; Hennig, Christoph; Yaita, Tsuyoshi; Bernhard, Gert

Book ID
115492593
Publisher
Royal Society of Chemistry
Year
2012
Tongue
English
Weight
777 KB
Volume
41
Category
Article
ISSN
1477-9226

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Stabilisation of tetravalent cerium in perchloric acid medium and measurement of the stability constants of its fluoride complexes using ion selective potentiometry
โœ R.M. Sawant; R.K. Rastogi; M.A. Mahajan; N.K. Chaudhuri ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 479 KB

The stability constants of the fluoride complexes of cerium (IV) in 1 M (HCIO,, NaClO,) medium have been measured potentiometrically using a fluoride ion-selective electrode. Quantitative oxidation of cerium to its tetravalent state and its stabilisation in the perchlorate medium were accomplished b