Two new dipicolinate complexes of cobalt, [Co(dpc) is nicotinamide and ina is isonicotinamide], have been prepared and characterized by thermal analysis, IR spectroscopy and X-ray diffraction techniques. The complex (1) crystallizes in triclinic system, whereas the complex (2) crystallizes in monoc
✦ LIBER ✦
Dinuclear cobalt and manganese squarate complexes with bidentate N-donor ligand: syntheses, crystal structures, spectroscopic, thermal and voltammetric studies
✍ Scribed by İ. Uçar; A. Bulut; O. Büyükgüngör; A. Karadağ
- Publisher
- Springer
- Year
- 2006
- Tongue
- English
- Weight
- 366 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0340-4285
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## Abstract The synthesis and crystal structures of three nonheme diiron(III) complexes with a tridentate N,N,O Schiff‐baseligand, 2‐({[2‐(dimethylamino)ethyl]imino}methyl)phenol (HL), are reported. Complexes [Fe~2~OL~2~(NCO)~2~] (1a) and [Fe~2~OL~2~(SAL)~2~]·H~2~O [SAL = __o__‐(CHO)C~6~H~4~O^–^] (