✦ LIBER ✦

Dinitrogen Functionalization with Terminal Alkynes, Amines, and Hydrazines Promoted by [(η 5 -C 5 Me 4 H) 2 Zr] 2 (μ 2 ,η 2 ,η 2 -N 2 ): Observation of Side-On and End-On Diazenido Complexes in the Reduction of N 2 to Hydrazine

✍ Scribed by Bernskoetter, Wesley H.; Pool, Jaime A.; Lobkovsky, Emil; Chirik, Paul J.

Book ID: 126397431
Publisher: American Chemical Society
Year: 2005
Tongue: English
Weight: 450 KB
Volume: 127
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja050387b

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

On the Origin of Dinitrogen Hydrogenatio

On the Origin of Dinitrogen Hydrogenation Promoted by [(η 5 -C 5 Me 4 H) 2 Zr] 2 (μ 2 ,η 2 ,η 2 -N 2 )

✍ Pool, Jaime A.; Bernskoetter, Wesley H.; Chirik, Paul J. 📂 Article 📅 2004 🏛 American Chemical Society 🌐 English ⚖ 89 KB

Lewis Adducts of the Side-On End-On Dini

Lewis Adducts of the Side-On End-On Dinitrogen-Bridged Complex [{(NPN)Ta}2(μ-H)2(μ-η1:η2-N2)] with AlMe3, GaMe3, and B(C6F5)3: Synthesis, Structure, and Spectroscopic Properties

✍ Felix Studt; Bruce A. MacKay; Samuel A. Johnson; Brian O. Patrick; Michael D. Fr 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 334 KB 👁 1 views

## Abstract Reaction of the side‐on end‐on dinitrogen complex [{(NPN)Ta}~2~(μ‐H)~2~(μ‐η^1^:η^2^‐N~2~)] (1; in which NPN=(PhNSiMe~2~CH~2~)~2~PPh), with the Lewis acids XR~3~ results in the adducts [{(NPN)Ta}~2~(μ‐H)~2~(μ‐η^1^:η^2^‐NNXR~3~)], XR~3~=GaMe~3~ (2), AlMe~3~ (3), and B(C~6~F~5~)~3~ (4). Th

Low-Temperature N–O Bond Cleavage and Re

Low-Temperature N–O Bond Cleavage and Reversible N–P Bond Formation Processes in the Reactions of the Unsaturated Anions [M 2 (η 5 -C 5 H 5 ) 2 (μ-PCy 2 )(μ-CO) 2 ] − (M = Mo, W) with the Nitrosyl Complex [Re(η 5 -C 5 H 4 Me)(CO) 2 (NO)] +

✍ Alvarez, M. Angeles; García, M. Esther; Ruiz, Miguel A.; Toyos, Adrián; Vega, M. 📂 Article 📅 2013 🏛 American Chemical Society 🌐 English ⚖ 809 KB

Reductive Cleavage of the N−N Bond of Hy

Reductive Cleavage of the N−N Bond of Hydrazine Induced by a Cationic Trinuclear Ruthenium Hexahydride Complex, [(Cp‘Ru)3(μ-H)6]X (Cp‘ = η5-C5Me5; X = 1/2 SO4, BF4, PF6, BPh4) and Dihydrogen

✍ Nakajima, Yumiko; Inagaki, Akiko; Suzuki, Hiroharu 📂 Article 📅 2004 🏛 American Chemical Society 🌐 English ⚖ 122 KB

Density Functional Study on the Hydrido

Density Functional Study on the Hydrido Migration to CO 2 and CS 2 of the (η 5 -C 5 H 4 (CH 2 ) 3 NH 3+ )MH(H 2 PCH 2 PH 2 ) (M = Fe, Ru, and Os) Complexes Promoted by the Protonated Amine Arm. Which Path Does the Reaction Take, Abstraction or Insertion?

✍ Matsubara, Toshiaki; Hirao, Kazuyuki 📂 Article 📅 2001 🏛 American Chemical Society 🌐 English ⚖ 149 KB