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Dinitrogen complexes of molybdenum(I)

โœ Scribed by George, T. Adrian; Seibold, C. D.

Book ID
127000123
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
298 KB
Volume
94
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

Kinetics of decomposition of a molybdenu
Kinetics of decomposition of a molybdenum(I) dinitrogen complex
โœ C.M. Elson ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 449 KB

Thecomplex, trans-[Mo(Nz)z(Ph,PCH,CH,PPH2),]+; decomposes with the loss of both Nz ligands in tetrahydrofuran-methanol (26% V/V)-0.1 N LiX electrolyte (X = Ct and CEO,-) via a first order dissociative mechanism. The rate constant of decomposition at 25" C in the presence of lithium chloride is 2.4 ?