𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Dimorphism of 2,2′:6′,2′′:6′′,2′′′-quater­pyridine

✍ Scribed by Rolland, M. ;van der Lee, A. ;Barboiu, M.


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
228 KB
Volume
61
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis


The title compound, C 20 H 14 N 4 , shows dimorphism, with crystals obtained from different solvents displaying different crystal structures. The main structural difference between the two polymorphs concerns the crystal packing, the dihedral angle between two nearly planar molecules being distinctly different. In the polymorph reported here, the molecule lies on an inversion centre.


📜 SIMILAR VOLUMES


Pyridine-2,6-dicarbohydrazide
✍ Jia, Bing ;Hu, Zong-Qiu ;Deng, Xiao-Tao ;Cheng, Cui-Xia ;Shi, Shao-Min 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 187 KB

The molecules of the title compound, C 7 H 9 N 5 O 2 , are almost completely planar. All bond lengths and angles show normal values. Hydrogen bonds of the form N-HÁ Á ÁO interconnect the molecules to form a three-dimensional network.

6,6′-Bis­(chloro­methyl)-2,2′-bi­pyridin
✍ Lindoy, Leonard F. ;McMurtrie, John C. ;Price, Jason R. 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 271 KB

Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.002 A Ê R factor = 0.025 wR factor = 0.069 Data-to-parameter ratio = 18.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

2,2′-Bis(2-nitro­benzylidene)pyridine-2,
✍ Jia, Bing ;Shi, Shaomin ;Luo, Feihua ;Hu, Zongqiu 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 339 KB

The title molecule, C 21 H 15 N 7 O 6 , has crystallographic twofold symmetry. In the crystal structure, intermolecular N-HÁ Á ÁO hydrogen bonds [HÁ Á ÁO = 2.125 (17) A ˚] link the molecules, forming one-dimensional chains along [001].

N-(2,6-Diisopropylphenyl)-6-[(2,6-diisop
✍ Aydın, Aslıhan ;Dinçer, Muharrem ;Dayan, Osman ;Çetinkaya, Bekir 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 758 KB

In the title compound, C 35 H 42 ClN 3 O 2 , molecules are linked to one another by intermolecular C-HÁ Á ÁO interactions, forming a C(12) chain running parallel to the [010] direction. The molecule has a nonplanar conformation. The benzene rings make dihedral angles of 72.72 (6) and 62.72 (6) with