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Dimethylarsenido-Transition Metal Complexes—Stable Organometallic Lewis Bases

✍ Scribed by Dr. Wolfgang Malisch; Dipl.-Chem. Max Kuhn

Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
180 KB
Volume
13
Category
Article
ISSN
0044-8249

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✦ Synopsis

Table 1. Substitution patterns, yields, and a number of characteristic NMR data for the products (101, ( l l ) , and (12). In all reactions the electrophile was added to a T H F solution of the lithium reagent at -80°C and the reaction mixture allowed to warm over 14h. All the compounds gave correct elemental analyses. Reaction Electrophile Yield NMR [6] to' .] 1. 3 s1lyl olefinic H n-pentyl iodide n-CSHiI benzaldehyde C6H5CH(OH) cyclohexanone (CH2)5C(OH) benzophenone (CsH5)2C(OH)

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