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Dimethyl germylene insertion into a strained C-Ge bond and matrix isolation of tetramethyl digermene Me2Ge=GeMe2

✍ Scribed by Paul Bleckmann; Rolf Minkwitz; Wilhelm P. Neumann; Michael Schriewer; Manfred Thibud; Bärbel Watta


Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
244 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis


Summw

Free tetramethyl digermene Me2Ge=GeMe2 is generated thermally from molten 7,8-digerma bicyclooctadienes[2.2.2] which are obtained by germylene (Me2Ge) insertion into the C-Ge bond of corresponding 7-germa norborna-