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Dimethoxydibenzophosphepine: An Axially Chiral Monophosphane for Efficient Asymmetric Catalysis

✍ Scribed by Dr. Elisabetta Alberico; Dr. Satyajit Karandikar; Prof. Serafino Gladiali

Book ID
112018925
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
210 KB
Volume
2
Category
Article
ISSN
1867-3880

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πŸ“œ SIMILAR VOLUMES

A new quinazoline-containing axially chi
A new quinazoline-containing axially chiral ligand for asymmetric catalysis
✍ Mary McCarthy; Patrick J Guiry πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 English βš– 94 KB

The rationale behind the design of an axially chiral quinazoline-containing phosphinamine ligand, 2-phenyl-Quinazolinap, is described. Its synthesis had two metal-catalysed couplings as the key steps. Enantiopure ligand was obtained after resolution and afforded up to 66% enantiomeric excess (ee) in