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Dimerization of 7,7,8,8-tetracyanoquinodimethane (TCNQ) radical anions via σ-bond formation: crystal structure and EPR properties of bis(dipyridyl)platinum(II)–TCNQ, [Pt(2,2'-dipy)2 2+(TCNQ)2 2−]

✍ Scribed by Dong, V. ;Endres, H. ;Keller, H. J. ;Moroni, W. ;Nöthe, D.


Book ID
111872993
Publisher
International Union of Crystallography
Year
1977
Weight
371 KB
Volume
33
Category
Article
ISSN
0567-7408

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## Abstract The reaction between [Mn(MAC)(H~2~O)~2~]Cl~2~·4H~2~O and LiTCNQ (MAC = 2,13‐dimethyl‐3,6,9,12,18‐pentaazabicyclo[12.3.1]octadeca‐1(18),2,12,14,16‐pentaene) affords a complex with the formula [Mn(MAC)(TCNQ)~2~] (1), whose crystal structure has been determined. Its structure consists of n