Dimer fluorescence of some β-dicarbonyl compounds
✍ Scribed by P. Nikolov; F. Fratev; I. Petkov; P. Markov
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 295 KB
- Volume
- 83
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Lmnmesamce and absorption spectra of Wlxarbonyl compounds have been studied over the concentratmn range lo-'lo-' hf. The temperature dependence of the emssion maG.ma was followed from 10 to 70°C. The em&on and long-wave absorption at h&x concentralons IS related to dimers of the enol tautomer. The assoc~ittton constant and change in free energy are evaluated * Gift to one of the authors (FF) by the A. von Humboldt Found&on. Germauy.
📜 SIMILAR VOLUMES
## Abstract The most convenient and direct route to α‐hydroxy‐β‐dicarbonyl compounds is the oxidation of readily accessible 1,3‐dicarbonyls. Hence, this type of oxidation is an intensively investigated field. In this short review, we present and compare α‐hydroxylations using various oxidants such