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Dimer fluorescence of some β-dicarbonyl compounds

✍ Scribed by P. Nikolov; F. Fratev; I. Petkov; P. Markov


Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
295 KB
Volume
83
Category
Article
ISSN
0009-2614

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✦ Synopsis


Lmnmesamce and absorption spectra of Wlxarbonyl compounds have been studied over the concentratmn range lo-'lo-' hf. The temperature dependence of the emssion maG.ma was followed from 10 to 70°C. The em&on and long-wave absorption at h&x concentralons IS related to dimers of the enol tautomer. The assoc~ittton constant and change in free energy are evaluated * Gift to one of the authors (FF) by the A. von Humboldt Found&on. Germauy.


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## Abstract The most convenient and direct route to α‐hydroxy‐β‐dicarbonyl compounds is the oxidation of readily accessible 1,3‐dicarbonyls. Hence, this type of oxidation is an intensively investigated field. In this short review, we present and compare α‐hydroxylations using various oxidants such