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Dilithium tetrachlorocuprate. A reagent for regioselective cleavage of epoxides to chlorohydrins.

✍ Scribed by James A. Ciaccio; Kenneth J. Addess; Thomas V. Bell

Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 207 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)83856-3

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✦ Synopsis

The title compound reacts with epoxides to selectively afford the vicinal chlorohydrin resulting from *attack by chloride at the less substituted carbon atom.

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