Dilatometric study of monovalent counter-ion association with polymethacrylate
β Scribed by J. Komiyama; Y. Takeda; M. Ando; T. Iijima
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 296 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0032-3861
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Volume changes accompanying the protonation of mono-, di-and poly-carboxylates in water were measured at 25 Β° using the circulation dilatometer. The carboxylates include alkali metal and tetra-alkylammonium (TAA) salts of acetic, pivalic, glutaric acid and samples of poly(methacrylic acid) (PMA) hav
Molecular dynamics simulations have been performed to obtain free energy profiles, for the association of Cs+ to 18-crown-6 in water. This is the first study of cation-crown ether interactions in aqueous solutions that explicitly includes the counter ion. This work also provides the first quantitat