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Diisopropyl tartrate-modified (E)-γ-[(menthofuryl)dimethylsilyl]-allyl boronate, an improved chiral reagent for the anti α-hydroxyallylation of aldehydes. Application to the enantioselective synthesis of (−)-swainsonine

✍ Scribed by J.A. Hunt; William R. Roush

Publisher: Elsevier Science
Year: 1995
Tongue: French
Weight: 253 KB
Volume: 36
Category: Article
ISSN: 0040-4039
DOI: 10.1016/0040-4039(94)02295-m

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## An enantioselective synthesis of and 1.2-diok via the reactions of aldehydes and the tartrate ester modified y(akoxysiiyl)allylboronate 2 has been developed. This method is most Mective in double asymmemk reuctions with chiral akiehydes. The stereoselective synthesis of syn and anti 1,2diol uni