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Diisophorone and related compounds. 21. Synthesis and nucleophilic reactions of 4, 4, 8- and 4, 6, 8-tribromodiisophorones

✍ Scribed by Kurzer, Frederick; Patel, Jayantilal N.


Book ID
121493635
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
974 KB
Volume
53
Category
Article
ISSN
0022-3263

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The synthesis of 1-and 2-aryl-substituted (aryl = Ph, 4-N0,-C6H,, and 4-MeO-C6H4) 4,6,8-trimethylazulenes (4 and 3, respectively) in moderate yields by direct arylation of 4,6,8-trimethylazulene (8) with the corresponding arylhydrazines 13 in the presence of Cu" ions in pyridine (see Scheme 4 ) as w