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Diiron Complex with Three Bridging Silyl Substituents

✍ Scribed by Simons, R. S. ;Tessier, C. A.


Book ID
114512011
Publisher
International Union of Crystallography
Year
1995
Tongue
English
Weight
211 KB
Volume
51
Category
Article
ISSN
0108-2701

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The reaction of the ligand HL Β΄(HCl) 2 (HL = 2,6di(aminomethyl)-4-tert-butyl-thiophenol) with MCl 2 in methanol in the presence of sodium methanolate and air affords the dinuclear complexes [L 3 M 2 ][ClO 4 ] 3 (M = Fe: 2, Co: 3) in 85% and 68% yield, respectively. Both complexes were characterized