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Diimidazo[1,5-a;1′,5′-d]pyrazine-5,10-dione

✍ Scribed by Castillejo Merchán, Alejandro ;Stoeckli-Evans, Helen


Book ID
104489443
Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
244 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound, C 8 H 4 N 4 O 2 , was prepared to explore the synthesis of some 4-substituted imidazoles. The molecule is centrosymmetric and almost planar. In the crystal structure, centrosymmetric dimers are formed via C-HÁ Á ÁN hydrogen bonds. The dimers are linked by further C-HÁ Á ÁN hydrogen bonds, forming a three-dimensional network.


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2,6-Dithiodecahydro-1H,5H-Diimidazo[4,5,
✍ Murugappa Vedachalam; Joseph H. Boyer 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 550 KB

## Abstract Thiourea condensed with 1,4‐diformyl‐2,3,5,6‐tetrahydroxypiperazine __2__ in the presence of hydrochloric acid to give 2,6‐dithiodecahydro‐1 H,5H‐diimidazo[4,5,‐b:4′,5′‐e]pyrazine __5__ isolated as the dihydrochloride salt. The salt __5__. 2HCl was converted to the free base __5__ by li