𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Dihyro- and tetrahydrofuran building blocks from 1,4:3,6-dianhydromannitol. 1. Synthesis of (1S,5R,7R)-endo-(-)- and (1S,5R,7S)-(-)-exo-brevicomin and (R)-(+)-dodecanolide

✍ Scribed by Cere, Vanda; Mazzini, Claudio; Paolucci, Claudio; Pollicino, Salvatore; Fava, Antonino

Book ID
115534688
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
760 KB
Volume
58
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Stereoselective synthesis of (+)-(1R,2S,
Stereoselective synthesis of (+)-(1R,2S,5S,7R)-2-hydroxy-exo-brevicomin
✍ D. Gautam; B. Venkateswara Rao 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 293 KB

A stereoselective approach for the synthesis of (+)-(1R,2S,5S,7R)-2-hydroxy-exo-brevicomin from L-ascorbic acid has been described. The key steps are highly stereoselective nucleophilic addition reaction on aldehyde 8 and also a single pot transformation of 15 to (+)-(1R,2S,5S,7R)-2-hydroxy-exo-brev

Pheromone Synthesis, CLXXXII. Synthesis
Pheromone Synthesis, CLXXXII. Synthesis of (1R,1′R,5′R,7′R)- and (1S,1′R,5′R,7′R)- 1-hydroxy-exo-Brevicomin, the Components of the Male-Produced Volatiles of the Mountain Pine Beetle,dendroctonus ponderosae
✍ Yokoyama, Yūsuke ;Mori, Kenji 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 491 KB

## Abstract Both (1__R__)‐ and (1__S__)‐hydroxy derivatives of (+)‐exo‐brevicomin {(1__R__,1′__R__,5′__R__,7′__R__)‐1‐(5′‐methyl‐6′,8′‐dioxabicyclo[3.2.1]‐octyl)ethanol (1) and its (1__S__)‐isomer (2)} were synthesized by employing Sharpless asymmetric dihydroxylation as the key reaction.