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Dihedral Angle and Bond Angle Dependence of Vicinal Proton-Fluorine Spin-Spin Coupling

✍ Scribed by Williamson, Kenneth L.; Li, Yuan-Fang; Hall, Frances H.; Swager, Susan

Book ID
127189177
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
429 KB
Volume
88
Category
Article
ISSN
0002-7863

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A dihedral angle-vicinal proton coupling
A dihedral angle-vicinal proton coupling constant correlation for the α–β bond of amino acid residues
✍ Kenneth D. Kopple; Gary R. Wiley; Ralph Tauke πŸ“‚ Article πŸ“… 1973 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 512 KB

## Abstract A coupling constant‐dihedral angle correlation for the Hο£ΏCΞ±ο£ΏCΞ²ο£ΏH system of amino acid residues in peptides has been derived from a set of model compounds covering the full range of dihedral angles. The expression obtained, __J__ = 11.0 cos~2~ ΞΈ βˆ’1.4 cos ΞΈ + 1.6 sin~2~ΞΈ, is close to thos