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Digital model of macromolecule crosslinking

✍ Scribed by A. V. Shyichuk

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
251 KB
Volume
61
Category
Article
ISSN
0021-8995

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✦ Synopsis

A digital model of the MWD changes under polymer crosslinking is described in detail. The model yields full MWD, its average molecular weights and other average parameters, and the gel point and gel fraction vs. the crosslinks number. T h e model is verified to be in essential agreement with the crosslinking theory predictions.

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## Abstract Equilibrium __P__–__V__–__T__ properties of randomly crosslinked amorphous polymer networks are modeled via molecular dynamics simulation for connectivity ratios between 1.0 and 1.5. The relation between connectivity ratio and network shrinkage is studied over a wide range of temperatur